AmazonGlobal Ship Orders Internationally. CCDC reference numbers The first process consisted of depositing cluster 5 by spin coating on a gold surface. Je la savais en moi, quelque part. Amazon Drive Cloud storage from Amazon. Access to the PDF text.

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Two approaches have been used to anchor the heterometallic complex on the surface and generate monolayers. The first process consisted of depositing cluster 5 by spin coating on a gold surface.

The second was the immersion of a gold surface into a cluster solution. Xrxy both procedures, the resulting deposits were analysed by STM scanning tunneling microscopyellipsometry and XPS X-ray photoelectron spectroscopy.

For the layers obtained by spin coating of a solution of cluster 5it was found that the cluster is not attached to the surface, but only deposited on it. In contrast, after immersion palladuim a gold substrate into a solution of 5 or 6anchoring of the complexes was clearly evidenced by XPS via the chemical shift of the S—2p binding energy toward lower binding energies.

Ces couches ont ensuite été analysées par STM Scanning tunneling microscopypar ellipsométrie et par spectroscopie XPS X-ray photoelectron spectroscopy.

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Mixed-metal clusters, Self-assembly, Gold surfaces, Spectroscopy, Scanning tunneling microscopy, X-ray photoelectron spectroscopy. Journal page Archives Contents list. Access to the text HTML.

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If you want to subscribe to this journal, see our rates You can purchase this item in Pay Per View: Synthesis of functional heterometallic complexes and clusters containing xrqy and palladium or platinum, their self-assembly on gold surfaces and X-ray photoelectron spectroscopic studies. Outline Masquer le plan. Preparation of the samples and analyses of the resulting layers.

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Palladium / Platine

You can move this window by clicking on the headline. Results and discussion Synthesis and characterization of the heterometallic complexes. Experimental part Preparation of the gold substrates. Electronic supplementary information ESI available: CCDC reference numbers